Understanding the Insertion Pathways and Chain Walking Mechanisms of α-Diimine Nickel Catalysts for α-Olefin Polymerization: A 13C NMR Spectroscopic Investigation
Author:
Affiliation:
1. Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, United States
2. Department of Chemistry, University of Houston, Houston, Texas 77204, United States
Funder
Division of Chemistry
Welch Foundation
Division of Graduate Education
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.macromol.7b01150
Reference50 articles.
1. New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins
2. Syndiotactic-specific polymerization of propene with a Ni-based catalyst
3. A Density Functional Study of the Mechanism of the Diimine−Nickel-Catalyzed Ethylene Polymerization Reaction
4. Monte-Carlo simulation of branching distribution in Ni-diimine catalyzed polyethylene
5. Mechanistic Studies of Pd(II)−α-Diimine-Catalyzed Olefin Polymerizations1
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