Experimental and Computational Evidence for 1,4-Diradical Intermediates in Reactions of Cobalt Fluorocarbene Complexes with Terminal Aryl-alkynes to give Metallacyclobutenes-Reference-Cited by-同舟云学术

Experimental and Computational Evidence for 1,4-Diradical Intermediates in Reactions of Cobalt Fluorocarbene Complexes with Terminal Aryl-alkynes to give Metallacyclobutenes

Published:2017-07-05 Issue:15 Volume:36 Page:2853-2860
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Lee Graham M.¹^ORCID,Leung Alicia S. C.¹,Harrison Daniel J.¹,Korobkov Ilia¹,Hughes Russell P.²^ORCID,Baker R. Tom¹^ORCID

Affiliation:

1. Department of Chemistry and Biomolecular Sciences and Centre for Catalysis Research and Innovation, University of Ottawa, 30 Marie Curie, Ottawa, Ontario K1N 6N5, Canada

2. Department of Chemistry, Dartmouth College, Hanover, New Hampshire 03755, United States

Funder

Canada Research Chairs

Natural Sciences and Engineering Research Council of Canada

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.7b00344

Reference38 articles.

1. Studies on the Mechanism of Intermolecular Enyne Metathesis: Kinetic Method and Alkyne Substituent Effects