DFT study on the reaction mechanism of the ring closing enyne metathesis (RCEYM) catalyzed by molybdenum alkylidene complexes-Reference-Cited by-同舟云学术

DFT study on the reaction mechanism of the ring closing enyne metathesis (RCEYM) catalyzed by molybdenum alkylidene complexes

Published:2014 Issue:11 Volume:43 Page:4573-4586
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Solans-Monfort Xavier¹²³

Affiliation:

1. Departament de Química

2. Universitat Autònoma de Barcelona

3. 08193 Bellaterra, Spain

Abstract

DFT calculations show that the RCEYM reaction catalyzed by Mo-based catalysts proceeds preferentially through an yne-then-ene mechanism and that the endo-/exo- selectivity mainly depends on sterics.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53242A

Reference95 articles.

1. Ruthenium Catalyzed Enyne Metathesis

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5. Olefin metathesis - A novel reaction for skeletal transformations of unsaturated hydrocarbons

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