Redox Properties of Monocyclooctatetraenyl Uranium(IV) and (V) Complexes: Experimental and Relativistic DFT Studies

Author:

Kias Farida1,Talbi Fatiha1,Elkechai Aziz1,Boucekkine Abdou2ORCID,Hauchard Didier3,Berthet Jean-Claude4,Ephritikhine Michel4

Affiliation:

1. Laboratoire de Physique et Chimie Quantique, Faculté des Sciences, Université Mouloud Mammeri de Tizi-Ouzou, 15000 Tizi-Ouzou, Algeria

2. Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1, Campus de Beaulieu, Rennes CEDEX 35042, France

3. Ecole Nationale Supérieure de Chimie de Rennes, ISCR, UMR 6226 CNRS, 11 allée de Beaulieu, CS 50837, Rennes CEDEX 35708, France

4. NIMBE, CEA, CNRS, Université Paris-Saclay, CEA-Saclay, 91191 Gif-sur-Yvette, France

Funder

Minist?re de l'Enseignement Sup?rieur et de la Recherche Scientifique

European Cooperation in Science and Technology

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference107 articles.

1. Bis(cyclooctatetraenyl)uranium (uranocene). A new class of sandwich complexes that utilize atomic f orbitals

2. Di-.pi.-cyclooctatetraenethorium

3. Preparation and properties of uranocene, di-.pi.-cyclooctatetraeneuranium(IV)

4. aMarks, T. J.; Streitwieser, A., Jr.InThe Chemistry of the Actinide Elements,2nd ed.Katz, J. J.; Seaborg, G. T.; Morss, L. R., Eds.Chapman and Hall:London, 1986; Vol.2, Chapter 22, pp1547–1571.

5. bBurns, C. J.; Eisen, M. S.InThe Chemistry of the Actinide and Transactinide Elements,3rd ed.Morss, L. R.; Edelstein, N.; Fuger, J.; Katz, J. J., Eds.Springer:Dordrecht, The Netherlands, 2006; Vol.5, Chapter 25, pp2799–2910.

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