Complexation and redox chemistry of neptunium, plutonium and americium with a hydroxylaminato ligand-Reference-Cited by-同舟云学术

Complexation and redox chemistry of neptunium, plutonium and americium with a hydroxylaminato ligand

Published:2021 Issue:40 Volume:12 Page:13343-13359
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Su Jing¹^ORCID,Cheisson Thibault²^ORCID,McSkimming Alex²,Goodwin Conrad A. P.³^ORCID,DiMucci Ida M.³,Albrecht-Schönzart Thomas⁴,Scott Brian L.⁵^ORCID,Batista Enrique R.¹^ORCID,Gaunt Andrew J.³^ORCID,Kozimor Stosh A.³^ORCID,Yang Ping¹^ORCID,Schelter Eric J.²^ORCID

Affiliation:

1. Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

2. P. Roy and Diana T. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, 231 S 34th St., Philadelphia, Pennsylvania 19104, USA

3. Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

4. Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, Florida 32306, USA

5. Materials and Physics Applications Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

Abstract

The coordination modes and electronic properties of a strongly coordinating hydroxylaminato ligand with Np, Pu and Am were investigated.Complexes were characterized by a range of experimental and computational techniques.

Funder

Basic Energy Sciences

Laboratory Directed Research and Development

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC03905A

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