Computational and Experimental Investigation of Alkene Hydrogenation by a Pincer-Type [P2Si]Rh Complex: Alkane Release via Competitive σ-Bond Metathesis and Reductive Elimination-Reference-Cited by-同舟云学术

Computational and Experimental Investigation of Alkene Hydrogenation by a Pincer-Type [P2Si]Rh Complex: Alkane Release via Competitive σ-Bond Metathesis and Reductive Elimination

Published:2019-03-07 Issue:7 Volume:38 Page:1493-1501
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Whited Matthew T.¹^ORCID,Trenerry Michael J.¹,DeMeulenaere Kaitlyn E.¹,Taylor Buck L. H.¹²^ORCID

Affiliation:

1. Department of Chemistry, Carleton College, Northfield, Minnesota 55057, United States

2. Department of Chemistry, University of Portland, Portland, Oregon 97203, United States

Funder

Camille and Henry Dreyfus Foundation

Division of Chemistry

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.8b00922

Reference39 articles.

1. Mechanism of the chlorotris(triphenylphosphine) rhodium(I)-catalyzed hydrogenation of alkenes. The reaction of chlorodihydridotris(triphenyl-phosphine)rhodium(III) with cyclohexene

2. cHartwig, J. F. In Organotransition Metal Chemistry: From Bonding to Catalysis; University Science Books: Sausalito, CA, 2010; pp 575–665.

3. Mechanism of Asymmetric Hydrogenation Catalyzed by a Rhodium Complex of (S,S)-1,2-Bis(tert-butylmethylphosphino)ethane. Dihydride Mechanism of Asymmetric Hydrogenation

4. eFelgdus, S.; Landis, C. R. In Computational Modeling of Homogeneous Catalysis; Maseras, F., Lledos, A., Eds. Kluwer: Dordrecht, 2002; Vol. 25, pp 107–135.

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