Preparation and Characterization of (iPrO)4WW(η2-dmpe)2(CO), (η1-O2CH)(iPrO)4WW(η2-dmpe)2(H), [H(η2-dmpe)WWO2]2(μ-O), and W2(O)4(μ-O)[W(η2-dmpe)2CO]2 (dmpe = Bisdimethylphosphinomethane), Compounds with W−W Bonds between Metal Atoms in Greatly Differing Oxidation States
Author:
Affiliation:
1. Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, Indiana 47405
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9705249
Reference11 articles.
1. An unbridged triple bond uniting d6 Mo(0) and d2 Mo(IV) atoms: bis[bis(dimethylphosphino)ethane]tetraisopropoxodimolybdenum
2. Electronic structure of asymmetric metal-metal multiple bonds: the d2-d6 molybdenum phosphine-alkoxide complexes X4Mo-Mo(Ph3)4 (X = OH, Cl)
3. Novel dimetal complex containing M(VI) and M(II) centers united by a short metal-metal bond: O3ReReCl2(Me2PCH2PMe2)2
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5. A Comparison of the Influences of Alkoxide and Thiolate Ligands on the Electronic Structure and Reactivity of Molybdenum(3+) and Tungsten(3+) Complexes. Preparation and Structures of M2(OtBu)2(StBu)4, [Mo(StBu)3((NO)]2, and W(StBu)3(NO)(py);Journal of the American Chemical Society;2001-09-07
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