A Comparison of the Influences of Alkoxide and Thiolate Ligands on the Electronic Structure and Reactivity of Molybdenum(3+) and Tungsten(3+) Complexes. Preparation and Structures of M2(OtBu)2(StBu)4, [Mo(StBu)3((NO)]2, and W(StBu)3(NO)(py)-Reference-Cited by-同舟云学术

A Comparison of the Influences of Alkoxide and Thiolate Ligands on the Electronic Structure and Reactivity of Molybdenum(3+) and Tungsten(3+) Complexes. Preparation and Structures of M2(OtBu)2(StBu)4, [Mo(StBu)3((NO)]2, and W(StBu)3(NO)(py)

Published:2001-09-07 Issue:39 Volume:123 Page:9652-9664
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Chisholm Malcolm H.¹,Davidson Ernest R.¹,Huffman John C.¹,Quinlan Kristine B.¹

Affiliation:

1. Contribution from the Department of Chemistry and Molecular Structure Center, Indiana University, Bloomington, Indiana 47405

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja001208n

Reference51 articles.

1. Hard and Soft Acids and Bases

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3. Reactions of (PMe3)4Ru(C2H4) and (DMPE)2Ru(C2H4) with Weak Proton-Donating Electrophiles HX (X = OAr, SAr, NHPh, PHPh). Synthesis of Complexes with Metal-Heteroatom Single Bonds

4. Hydrocarbon Bond Dissociation Energies

5. Solution Calorimetric Investigation of Oxidative Addition of HEAr (E = O, S, Se; Ar = C6H4X, X = CH3, H, Cl, NO2) to (PMe3)4Ru(C2H4): Relationship between HEAr Acidity and Enthalpy of Reaction

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