Selective Protonation at a C−F Bond in the Presence of an Iridium−Methyl Bond Gives Diastereoselective Carbon−Fluorine Bond Activation and Carbon−Carbon Bond Formation. A New Path to Carbon Stereocenters Bearing Fluorine Atoms
Author:
Affiliation:
1. Departments of Chemistry, 6128 Burke Laboratory, Dartmouth College, Hanover, New Hampshire 03755, and University of Delaware, Newark, Delaware 19716
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om020718i
Reference34 articles.
1. Synthetic Applications of Electrophilic Fluorodesilylation
2. Electrophilic Fluorination Mediated by Cinchona Alkaloids: Highly Enantioselective Synthesis of α-Fluoro-α-phenylglycine Derivatives
3. The Mechanism of Catalytic Enantioselective Fluorination: Computational and Experimental Studies
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