Synthesis, structure, and reactivity of iridium perfluorocarbene complexes: regio- and stereo-specific addition of HCl across a metal carbon double bond-Reference-Cited by-同舟云学术

Synthesis, structure, and reactivity of iridium perfluorocarbene complexes: regio- and stereo-specific addition of HCl across a metal carbon double bond

Published:2015 Issue:45 Volume:44 Page:19528-19542
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yuan Jian¹²³⁴⁵,Bourgeois Cheryl J.¹²³⁴⁵,Rheingold Arnold L.¹⁶⁷⁵,Hughes Russell P.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. 6128 Burke Laboratory

3. Dartmouth College

4. Hanover

5. USA

6. University of California

7. San Diego

Abstract

Addition of HCl to perfluorocarbene complexes of iridium occurs regiospecifically and stereospecifically.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02275D

Reference67 articles.

1. OLEFIN METATHESIS: BIG-DEAL REACTION

2. Olefin metathesis

3. Theoretical comparison between nucleophilic and electrophilic transition metal carbenes using generalized molecular orbital and configuration interaction methods

4. Chemical bonding in transition metal carbene complexes

5. Density functional study of the first-row transition-metal complexes M–CH2, M–CHF, and M–CF2

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