Experimental and Theoretical Evaluation of Energetics for Nucleophilic Solvent Participation in the Solvolysis of Tertiary Alkyl Chlorides on the Basis of Gas Phase Bridgehead Carbocation Stabilities-Reference-Cited by-同舟云学术

Experimental and Theoretical Evaluation of Energetics for Nucleophilic Solvent Participation in the Solvolysis of Tertiary Alkyl Chlorides on the Basis of Gas Phase Bridgehead Carbocation Stabilities

Published:2000-07-14 Issue:30 Volume:122 Page:7351-7357
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Takeuchi Ken'ichi¹,Takasuka Masaaki¹,Shiba Eiji¹,Kinoshita Tomomi¹,Okazaki Takao¹,Abboud José-Luis M.¹,Notario Rafael¹,Castaño Obis¹

Affiliation:

1. Contribution from the Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan, Instituto de Química Física, “Rocasolano”, C. S. I. C. E-28006 Madrid, Spain, and Departamento de Química Física, Universidad de Alcalá, E-28871, Alcalá de Henares (Madrid), Spain

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja0004635

Reference62 articles.

1. Photochemical and thermal denitrogenations of azoalkanes as mechanistic probes for the diradical intermediates involved in the di-.pi.-methane rearrangement of dibenzobarrelene

2. The SN2-SN1 spectrum. 2. Quantitative treatments of nucleophilic solvent assistance. A scale of solvent nucleophilicities

Cited by 52 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. A thermodynamic approach to analyzing relative permittivity and solvent mole fraction models, and application to S_N1 reactions;Physical Chemistry Chemical Physics;2024

2. Solvatochromic correlation analysis of monomolecular SN1/E1 heterolysis reactions of tertiary haloalkanes;Journal of Molecular Liquids;2021-02

3. Properties of the tert-butyl halide solvolysis transition states;Physical Chemistry Chemical Physics;2021

4. The decomposition of triphenylimidazole-para -acetate follows specific base catalysis and can be conveniently followed by fluorescence;Luminescence;2019-02-11

5. Nucleophilic Influences and Origin of the S N 2 Allylic Effect;Chemistry – A European Journal;2018-07-18