Properties of the tert-butyl halide solvolysis transition states
Author:
Affiliation:
1. Department of Chemistry
2. University College London
3. London WC1H 0AJ
4. UK
5. Centro de Química Estrutural (CQE), Faculdade de Ciências
6. Universidade de Lisboa
7. Campo Grande
8. Lisboa
9. Portugal
Abstract
The rate of solvolysis of tert-butyl halides is increased by both nucleophilic and electrophilic solvents.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2021/CP/D0CP05099G
Reference42 articles.
1. 56. Mechanism of substitution at a saturated carbon atom. Part V. Hydrolysis of tert.-butyl chloride
2. Is the tert-Butyl Chloride Solvolysis the Most Misunderstood Reaction in Organic Chemistry? Evidence Against Nucleophilic Solvent Participation in the tert-Butyl Chloride Transition State and for Increased Hydrogen Bond Donation to the 1-Adamantyl Chloride Solvolysis Transition State
3. A semitheoretical multiparameter approach to correlate solvent effects on reactions and equilibria
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