Dimeric Rhodium μ-Silylene and μ-η2-Silyl Complexes: Catalytic Silicon−Silicon Bond Formation and X-ray Structures of [{Pri2PCH2CH2PPri2}Rh]2(μ-SiRR‘)2 (R = R‘ = Ph and R = Me, R‘ = Ph) and [{Pri2PCH2CH2PPri2}Rh(H)]2(μ-η2-H−SiMe2)2
Author:
Affiliation:
1. Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, British Columbia, Canada V6T 1Y6
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om980651s
Reference32 articles.
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2. Harrod, J. F.; Chalk, A. J. InOrganic Syntheses Via Metal Carbonyls; Wender, I., Pino, P., Eds.; Wiley: New York, 1977; p 690.
3. The Hydrosilylation Reaction
4. Mechanistic Aspects of Transition-Metal Catalyzed Dehydrogenative Silane Coupling Reactions
5. Transition Metal-Catalyzed Synthesis of Silicon Polymers
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