Preparation of Bis(μ3-silylyne) Complexes via Consecutive Si–H Bond Cleavage at a Triruthenium Site
Author:
Affiliation:
1. Department of Chemical Science and Engineering, School of Materials and Chemical Technology, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan
2. JST, ACT-C, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan
Funder
Creations of Advanced Catalytic Transformation for the Sustainable Manufacturing at Low Energy, Low Environmental Load
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.7b00548
Reference65 articles.
1. Metal–dihydrogen and σ-bond coordination: the consummate extension of the Dewar–Chatt–Duncanson model for metal–olefin π bonding
2. Metal Dihydrogen and σ-Bond Complexes
3. Reactions of Hydrosilanes with Transition Metal Complexes
4. Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products
5. Reactions of Hydrosilanes with Transition-Metal Complexes: Formation of Stable Transition-Metal Silyl Compounds
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1. Synthesis of a homoleptic tris(silylene)–palladium(0) complex and a silylyne-bridged tetranuclear palladium cluster;Chemical Communications;2023
2. σ-Coordination of a P–H Bond at a Sterically Demanding Diruthenium Site: Tautomerization between Agostic μ-Phosphane and μ-Phosphanido Complexes via an η2-P–H Bond Cleavage;Organometallics;2018-01-19
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