Air-Stable, Electron-Deficient Fe(II) Catalytic Porphyrins. Characterization and Molecular Structures of Rare High Spin Fe(II) Hexacoordinated Porphyrins

Author:

Barkigia Kathleen M.1,Palacio Magali1,Sun Yu1,Nogues Marc1,Renner Mark W.1,Varret François1,Battioni Pierrette1,Mansuy Daniel1,Fajer Jack1

Affiliation:

1. Materials Science Department, Brookhaven National Laboratory, Upton, New York 11973-5000, UMR 8601, Université Paris V, 45 Rue des Saints-Pères, 75270 Paris Cedex 06, France, and Laboratoire de Magnétisme et d'Optique, Université de Versailles, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference15 articles.

1. Extensive reviews relevant to the ensuing discussion can be found inThe Porphyrin Handbook; Kadish, K. M., Smith, K. M., Guilard, R., Eds.; Academic Press:  New York, 2000. (a) Mansuy, D.; Battioni, P. Vol. 4; p 1; (b) Poulos, T. L. Vol. 4; p 189; (c) Groves, J. T.; Shalyaev, K.; Lee, J. Vol. 4; p 17; (d) Suslick, K. S. Vol. 4; p 41; (e) Weiss, R.; Gold, A.; Trautwein, A. X.; Terner, J. Vol. 4; p 65; (f) Meunier, B.; Robert, A.; Pratviel, G.; Bernardou, J. Vol. 4; p 119; (g) Walker, F. A. Vol. 5; p 81; (h) La Mar, G. N.; Satterlee, J. D.; De Ropp, J. S. Vol. 5; p 185; (i) Scheidt, W. R. Vol. 3; p 49; (j) Kadish, K. M.; Van Caemelbecke, E.; Royal, G. Vol. 8; p 1; (k) Lecomte, C.; Rohmer, M. M.; Bernard, M. Vol. 7; p 39; (l) Senge, M. O. Vol. 1; p 239; (m) Raman, C. S.; Martásek, P.; Masters, B. S. S. Vol. 4; p 293; (n) Shelnutt, J. A. Vol. 7; p 167.

2. Polyhaloporphyrins:  Unusual Ligands for Metals and Metal-Catalyzed Oxidations

3. New Metalloporphyrins with Extremely Altered Redox Properties:  Synthesis, Structure, and Facile Reduction to Air-Stable π-Anion Radicals of Zinc and Nickel β-Heptanitroporphyrins

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