Acid-Catalyzed Breakdown of Alkoxide and Thiolate Ion Adducts of Benzylidene Meldrum's Acid, Methoxybenzylidene Meldrum's Acid and Thiomethoxybenzylidene Meldrum's Acid-Reference-Cited by-同舟云学术

Acid-Catalyzed Breakdown of Alkoxide and Thiolate Ion Adducts of Benzylidene Meldrum's Acid, Methoxybenzylidene Meldrum's Acid and Thiomethoxybenzylidene Meldrum's Acid

Published:1999-11-01 Issue:24 Volume:64 Page:8829-8839
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Bernasconi Claude F.¹,Ketner Rodney J.¹,Brown Shoshana D.¹,Chen Xin¹,Rappoport Zvi¹

Affiliation:

1. Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064, and Department of Organic Chemistry, The Hebrew University of Jerusalem, Jerusalem 91904, Israel

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo991041k

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2. Kinetics of reactions of thiolate ions with .alpha.-nitro .beta.-substituted stilbenes in 50% Me2SO-50% water. Observation of the intermediate in nucleophilic vinylic substitution reactions

3. Reaction of N-methylmethoxyamine with .beta.-methoxy-.alpha.-nitrostilbene. First direct observation of the intermediate in a nucleophilic vinylic substitution with an amine nucleophile

4. Kinetic Analysis of Elementary Steps in Nucleophilic Vinylic Substitution Reactions of .alpha.-Nitro-.beta.-X-stilbenes (X = OCH2CF3, OCH3, NO2) with Various Nucleophiles. Detection of the Intermediate in the Reaction of .alpha.-Nitro-.beta.-(2,2,2-trifluoroethoxy)stilbene with HOCH2CH2S- and of .beta.-Methoxy-.alpha.-nitrostilbene with CF3CH2O-

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