Nucleophilic substitution in ionizable Fischer thiocarbene complexes: steric effect of the alkyl substituent on the heteroatom-Reference-Cited by-同舟云学术

Nucleophilic substitution in ionizable Fischer thiocarbene complexes: steric effect of the alkyl substituent on the heteroatom

Published:2015 Issue:12 Volume:44 Page:5520-5534
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Andrada Diego M.¹²³⁴⁵,Zoloff Michoff Martin E.⁶²³⁴⁵,de Rossi Rita H.¹²³⁴⁵,Granados Alejandro M.¹²³⁴⁵

Affiliation:

1. Departamento de Química Orgánica

2. INFIQC

3. CONICET and Facultad de Ciencias Químicas

4. Universidad Nacional de Córdoba

5. Ciudad Universitaria X5000HUA

6. Departamento de Matemática y Física

Abstract

A kinetic study of the aminolysis reaction of Fischer thiocarbene complexes unravels the main factors ruling the reactivity and establishes the consequences of changing the π-donor strength.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03618B

Reference146 articles.

1. Some recent applications of Fischer carbenemetal complexes in organic synthesis

2. Catalytic Transmetalation from Group 6 Fischer Carbene Complexes: An Emerging Powerful Tool in Organic Synthesis

3. Fischer Carbene Complexes: Beautiful Playgrounds To Study Single Electron Transfer (SET) Reactions

4. Computational and experimental tools in solving some mechanistic problems in the chemistry of Fischer carbene complexes

5. Fischer Carbene Complexes in Organic Synthesis: Metal-Assisted and Metal-Templated Reactions

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