Rates of Hexadehydro-Diels–Alder (HDDA) Cyclizations: Impact of the Linker Structure
Author:
Affiliation:
1. Department of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, United States
Funder
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol502131r
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2. Cycloaromatization of a non-conjugated polyenyne system: Synthesis of 5H-benzo[d]fluoreno[3,2-b]pyrans via diradicals generated from 1-[2-{4-(2-alkoxymethylphenyl)butan-1,3-diynyl}]phenylpentan-2,4-diyn-1-ols and trapping evidence for the 1,2-didehydrobenzene diradical
3. Scope of the Thermal Cyclization of Nonconjugated Ene–Yne–Nitrile System: A Facile Synthesis of Cyanofluorenol Derivatives
4. The hexadehydro-Diels–Alder reaction
5. Tactics for probing aryne reactivity: mechanistic studies of silicon–oxygen bond cleavage during the trapping of (HDDA-generated) benzynes by silyl ethers
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