Tactics for probing aryne reactivity: mechanistic studies of silicon–oxygen bond cleavage during the trapping of (HDDA-generated) benzynes by silyl ethers-Reference-Cited by-同舟云学术

Tactics for probing aryne reactivity: mechanistic studies of silicon–oxygen bond cleavage during the trapping of (HDDA-generated) benzynes by silyl ethers

Published:2014 Issue:2 Volume:5 Page:545-550
ISSN:2041-6520
Container-title:Chem. Sci.
language:en
Short-container-title:Chem. Sci.

Author:

Hoye Thomas R.¹²³,Baire Beeraiah¹²³,Wang Tao¹²³

Affiliation:

1. Department of Chemistry

2. University of Minnesota

3. Minneapolis, USA

Abstract

Mechanistic features of the trapping reaction of an HDDA-generated aryne by pendant silyl ethers were probed using, e.g., an intramolecular clock reaction (cf. k₂).

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/SC/C3SC53014K

Reference18 articles.

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3. Thermolysis of 1,3,8-Nonatriyne: Evidence for Intramolecular [2 + 4] Cycloaromatization to a Benzyne Intermediate

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