Benzoannelation Stabilizes the dxy1 State of Low-Spin Iron(III) Porphyrinates

Author:

Ikeue Takahisa1,Handa Makoto1,Chamberlin Adam2,Ghosh Abhik2,Ongayi Owendi3,Vicente M. Graça H.3,Ikezaki Akira4,Nakamura Mikio45

Affiliation:

1. Department of Chemistry, Faculty of Material Science, Shimane University, 1060 Nishikawatsu-cho, Matsue-shi, Shimane 690-8504, Japan

2. Department of Chemistry and the Center for Theoretical and Computational Chemistry, University of Tromso, Breivika, N-9037 Tromso, Norway

3. Department of Chemistry, Louisiana State University, Baton Rouge, Louisiana 70803, United States

4. Department of Chemistry, School of Medicine, Toho University, Ota-ku, Tokyo 143-8540, Japan

5. Division of Chemistry, Graduate School of Science, Toho University, Funabashi 274-8510, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference56 articles.

1. Scheidt, W. R.InThe Porphyrin Handbook;Kadish, K. M., Smith, K. M., Guilard, R., Eds.Academic Press:San Diego, CA, 2000; Vol.3, Chapter XX, pp49−112.

2. Walker, F. A.InThe Porphyrin Handbook;Kadish, K. M., Smith, K. M., Guilard, R., Eds.Academic Press:San Diego, CA, 2000; Vol.5, Chapter 36, pp81−183.

3. Pulsed EPR and NMR Spectroscopy of Paramagnetic Iron Porphyrinates and Related Iron Macrocycles:  How To Understand Patterns of Spin Delocalization and Recognize Macrocycle Radicals

4. Models of the Bis-Histidine-Ligated Electron-Transferring Cytochromes. Comparative Geometric and Electronic Structure of Low-Spin Ferro- and Ferrihemes

5. Electronic structures of highly deformed iron(III) porphyrin complexes

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