Mechanism of the Reactions of Synthetic Fe−S-Based Clusters with PhCOCl: Parallel Pathways Involving Free and Coordinated Thiolate as Nucleophiles
Author:
Affiliation:
1. Chemistry, School of Natural Sciences, University of Newcastle, Newcastle upon Tyne, NE1 7RU, U.K.
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic0612707
Reference30 articles.
1. The Clusters of Nitrogenase: Synthetic Methodology in the Construction of Weak-Field Clusters
2. Mechanistic Studies on Synthetic Fe−S-Based Clusters and Their Relevance to the Action of Nitrogenases
3. Proton transfer to synthetic Fe–S-based clusters
4. Reactivity of [Fe4S4(SR)4]2-,3- Clusters with Sulfonium Cations: Analogue Reaction Systems for the Initial Step in Biotin Synthase Catalysis
5. Electron exchange kinetics of [Fe4S4(SR)4]2-/[Fe4S4(SR)4]3- and [Fe4Se4(SR)4]2-/[Fe4Se4(SR)4]3- systems. Estimates of the intrinsic self-exchange rate constant of 4-Fe sites in oxidized and reduced ferredoxins
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1. Structural insight into halide-coordinated [Fe4S4XnY4−n]2− clusters (X, Y = Cl, Br, I) by XRD and Mössbauer spectroscopy;Dalton Transactions;2023
2. Binding Substrates to Synthetic Fe-S-Based Clusters and the Possible Relevance to Nitrogenases;Bioinspired Catalysis;2014-08-22
3. Site specific ligand substitution in cubane-type Mo3FeS44+ clusters: Kinetics and mechanism of reaction and isolation of mixed ligand Cl/SPh complexes;Dalton Transactions;2010
4. Involvement of thiolate ligands in binding substrates to Fe–S clusters;Dalton Transactions;2008
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