Intrinsic Acidity of Dimethylhalonium Ions:  Evidence for Hyperconjugation in Dimethylhalonium Ylides in the Gas Phase

Author:

Noronha Leandro A1,Judson Thiago J. L.1,Dias Jacques F.1,Santos Leonardo S.1,Eberlin Marcos N.1,Mota Claudio J. A.1

Affiliation:

1. Universidade Federal do Rio de Janeiro, Instituto de Química, Departamento Química Orgânica, Cidade Universitária CT Bloco A, 21949-900 Rio de Janeiro, Brazil, Universidade do Estado do Rio de Janeiro, Faculdade de Tecnologia, Resende, Brazil, and Universidade Estadual de Campinas, Laboratório Thomson de Espectrometria de Massas, Instituto de Química, Campinas, Brazil

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference58 articles.

1. (a) Olah, G. A.Halonium Ions; Wiley:  New York, 1975.

2. (b) Olah, G. A.; Laali, K. K.; Wang, Q.; Prakash, G. K. S.Onium Ions; Wiley:  New York, 1998; chapter 6.

3. The Halogenation of Ethylenes

4. stable carbonium ions. lvii catalysts with olefins.ang. .ang.

5. Stable carbonium ions. LXII. Halonium ion formation via neighboring halogen participation: ethylenehalonium, propylenehalonium, and 1,2-dimethylethylenehalonium ions

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