The salts of chloronium ions R–Cl+–R (R = CH3 or CH2Cl): formation, thermal stability, and interaction with chloromethanes
Author:
Affiliation:
1. Vorozhtsov Institute of Organic Chemistry
2. Siberian Branch of Russian Academy of Sciences (SB RAS)
3. Novosibirsk 630090
4. Russia
5. Department of Natural Science
Abstract
Reactivity of chloronium cations: the interaction with CH2Cl2 or CHCl3 under ambient conditions with the formation of the final products, CH3–Cl+–CH3 and CCl4.
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP00946H
Reference22 articles.
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2. G. A. Olah , K. K.Laali, Q.Wang and G. K. S.Prakash, Onium Ions, Wiley, New York, 1998, ch. 6
3. Evidence for a Symmetrical Fluoronium Ion in Solution
4. Search for a Symmetrical C–F–C Fluoronium Ion in Solution: Kinetic Isotope Effects, Synthetic Labeling, and Computational, Solvent, and Rate Studies
5. Quantitative Assessment of the Multiplicity of Carbon–Halogen Bonds: Carbenium and Halonium Ions with F, Cl, Br, and I
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