Methane Activation by Naked Rh+ Atoms. A Theoretical Study
Author:
Affiliation:
1. Department of Physics, Stockholm University, S-113 85 Stockholm, Sweden
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp981291p
Reference34 articles.
1. Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H)
2. Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups
3. Mechanism of arene carbon-hydrogen bond activation by (C5Me5)Rh(PMe3)(H)Ph. Evidence for arene precoordination
4. Oxidative addition of the carbon-hydrogen bonds of neopentane and cyclohexane to a photochemically generated iridium(I) complex
5. Activation of methane by iridium complexes
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