IR spectroscopic characterization of [M,C,2H]+ (M = Ru and Rh) products formed by reacting 4d transition metal cations with oxirane: Spectroscopic evidence for multireference character in RhCH2+-Reference-Cited by-同舟云学术

IR spectroscopic characterization of [M,C,2H]⁺ (M = Ru and Rh) products formed by reacting 4d transition metal cations with oxirane: Spectroscopic evidence for multireference character in RhCH₂⁺

Published:2024 Issue:15 Volume:26 Page:11445-11458
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wensink Frank J.¹^ORCID,Smink Corry E.¹,Stevenson Brandon C.²,Steele Ryan P.²,Bakker Joost M.¹^ORCID,Armentrout P. B.²^ORCID

Affiliation:

1. Radboud University, Institute for Molecules and Materials, HFML-FELIX, Toernooiveld 7, 6525 ED Nijmegen, The Netherlands

2. Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, USA

Abstract

A combination of infrared multiple-photon dissociation (IRMPD) action spectroscopy and quantum chemical calculations was employed to investigate the [M,C,2H]+ (M = Ru and Rh) species.

Funder

National Science Foundation

U.S. Department of Energy

Nederlandse Organisatie voor Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CP/D4CP00012A

Reference69 articles.

1. Organometallic alkane CH activation

2. Lessons from nature: unraveling biological CH bond activation

3. Gas-Phase Catalysis by Atomic and Cluster Metal Ions: The Ultimate Single-Site Catalysts

4. Selective Activation of Alkanes by Gas-Phase Metal Ions

5. Models in Catalysis

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