Fragility-Confinement Effects: Apparent Universality as a Function of Scaled Thickness in Films of Freely Deposited, Linear Polymer and Its Absence in Densely Grafted Brushes
Author:
Affiliation:
1. Department of Materials Science and Engineering and ‡Department of Chemical and Biological Engineering, Northwestern University, Evanston, Illinois 60208, United States
Funder
Dow Chemical Company
Northwestern University
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.macromol.5b02489
Reference99 articles.
1. Size-Dependent Depression of the Glass Transition Temperature in Polymer Films
2. Molecular weight dependence of reductions in the glass transition temperature of thin, freely standing polymer films
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4. The distribution of glass-transition temperatures in nanoscopically confined glass formers
5. Glass Transition Dynamics and Surface Layer Mobility in Unentangled Polystyrene Films
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