Eliminating the <i>T</i><sub>g</sub>-Confinement Effect in Polystyrene Films: Extraordinary Impact of a 2 mol % 2-Ethylhexyl Acrylate Comonomer-Reference-Cited by-同舟云学术

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Eliminating the T_g-Confinement Effect in Polystyrene Films: Extraordinary Impact of a 2 mol % 2-Ethylhexyl Acrylate Comonomer

Published:2022-10-27 Issue:21 Volume:55 Page:9601-9611
ISSN:0024-9297
Container-title:Macromolecules
language:en
Short-container-title:Macromolecules

Author:

Wang Tong¹,Hu Sumeng¹,Zhang Sipei²,Peera Asghar²,Reffner John²,Torkelson John M.¹³^ORCID

Affiliation:

1. Department of Chemical and Biological Engineering, Northwestern University, Evanston, Illinois60208, United States

2. The Dow Chemical Company, 400 Arcola Road, Collegeville, Pennsylvania19426, United States

3. Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois60208, United States

Funder

Dow Chemical Company

Publisher

American Chemical Society (ACS)

Subject

Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.macromol.2c01917

Reference85 articles.

1. Relaxation in glassforming liquids and amorphous solids

2. 50th Anniversary Perspective: Challenges in the Dynamics and Kinetics of Glass-Forming Polymers

3. Interface and surface effects on the glass-transition temperature in thin polymer films

4. Size-Dependent Depression of the Glass Transition Temperature in Polymer Films

5. Effect of strongly favorable substrate interactions on the thermal properties of ultrathin polymer films

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Random Copolymers Based on 2‐Ethylhexyl Acrylate Exhibit Unusual Glass Transition Breadth and Facile Autonomous Self‐Healing over a Broad Composition Range;Macromolecular Rapid Communications;2024-08-16

2. Tunability and molecular weight dependence of the physical aging behavior of polystyrene and poly(methyl methacrylate) films;Polymer Engineering & Science;2024-06-17

3. Eliminating the Tg-confinement and fragility-confinement effects in poly(4-methylstyrene) films by incorporation of 3 mol % 2-ethylheyxl acrylate comonomer;The Journal of Chemical Physics;2024-01-18

4. Rapid stress relaxation of high‐T_g conjugated polymeric thin films;Journal of Polymer Science;2023-11-11

5. Reducing the Bulk Fragility and Suppressing the Fragility-Confinement Effect in Polystyrene with Very Low Levels of 2-Ethylhexyl Acrylate Comonomer;Macromolecules;2023-05-09

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