Mechanism of the Regio- and Stereoselective Cyclopolymerization of 1,6-Hepta- and 1,7-Octadiynes by High Oxidation State Molybdenum–Imidoalkylidene N-Heterocyclic Carbene Initiators-Reference-Cited by-同舟云学术

Mechanism of the Regio- and Stereoselective Cyclopolymerization of 1,6-Hepta- and 1,7-Octadiynes by High Oxidation State Molybdenum–Imidoalkylidene N-Heterocyclic Carbene Initiators

Published:2015-07-14 Issue:14 Volume:48 Page:4768-4778
ISSN:0024-9297
Container-title:Macromolecules
language:en
Short-container-title:Macromolecules

Author:

Herz Katharina,Unold Jörg¹,Hänle Johannes,Schowner Roman,Sen Suman,Frey Wolfgang,Buchmeiser Michael R.¹

Affiliation:

1. Institute of Textile Chemistry and Chemical Fibers, Körschtalstr. 26, D-73770 Denkendorf, Germany

Funder

Deutsche Forschungsgemeinschaft

Publisher

American Chemical Society (ACS)

Subject

Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.macromol.5b01185

Reference65 articles.

1. Carboxylate-Based Molybdenum Alkylidene Catalysts: Synthesis, Characterization, and Use as Initiators for 1,6-Heptadiyne Cyclopolymerizations

2. Preparation of Biscarboxylato Imido Alkylidene Complexes of Molybdenum and Cyclopolymerization of Diethyldipropargylmalonate To Give a Polyene Containing only Six-Membered Rings

3. Living Cyclopolymerization of 1,6-Heptadiyne Derivatives Using Well-Defined Alkylidene Complexes: Polymerization Mechanism, Polymer Structure, and Polymer Properties

4. Living cyclopolymerization of diethyl dipropargylmalonate by Mo(CH-t-Bu)(NAr)[OCMe(CF3)2]2 in dimethoxyethane

5. Stereo- and regioselective cyclopolymerization of chiral 1,7-octadiynes

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