Further Proof of Unconventional Conjugation via Disiloxane Bonds: Double Decker Sesquioxane [vinylMeSi(O0.5)2(PhSiO1.5)8(O0.5)2SiMevinyl] Derived Alternating Terpolymers Give Excited-State Conjugation Averaging That of the Corresponding Copolymers-Reference-Cited by-同舟云学术

Further Proof of Unconventional Conjugation via Disiloxane Bonds: Double Decker Sesquioxane [vinylMeSi(O_0.5)₂(PhSiO_1.5)₈(O_0.5)₂SiMevinyl] Derived Alternating Terpolymers Give Excited-State Conjugation Averaging That of the Corresponding Copolymers

Published:2022-09-13 Issue:18 Volume:55 Page:8106-8116
ISSN:0024-9297
Container-title:Macromolecules
language:en
Short-container-title:Macromolecules

Author:

Zhang Zijing¹,Guan Jun¹,Ansari Ramin²,Kieffer John¹^ORCID,Yodsin Nuttapon³^ORCID,Jungsuttiwong Siriporn⁴^ORCID,Laine Richard M.¹⁵^ORCID

Affiliation:

1. Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48105, United States

2. Department of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48105, United States

3. National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), Pathum Thani 12120, Thailand

4. Department of Chemistry, Faculty of Science, Ubon Ratchathani University, Ubon Ratchathani 34190, Thailand

5. Department of Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan 48105, United States

Funder

Division of Chemistry

Publisher

American Chemical Society (ACS)

Subject

Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.macromol.2c01355

Reference41 articles.

1. Polyhedral oligosilsesquioxanes and their homo derivatives

2. Silsesquioxanes

3. Bridged Polysilsesquioxanes. Highly Porous Hybrid Organic-Inorganic Materials

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1. Thiol‐ene polymerization of double‐decker‐shaped phenyl‐substituted silsesquioxanes and thiol monomers;Journal of Polymer Science;2024-04-09

2. Conjugation in polysiloxane copolymers via unexpected Si-O-Si dπ-pπ overlap, a second mechanism?;Polymer Journal;2024-03-14

3. Conjugation through Si–O–Si bonds, silsesquioxane (SQ) half cage copolymers, extended examples via SiO_0.5/SiO_1.5 units: multiple emissive states in violation of Kasha's rule;Dalton Transactions;2024

4. Distinct insight into the use of difunctional double-decker silsesquioxanes as building blocks for alternating A–B type macromolecular frameworks;Inorganic Chemistry Frontiers;2023