Conjugation through Si–O–Si bonds, silsesquioxane (SQ) half cage copolymers, extended examples via SiO0.5/SiO1.5 units: multiple emissive states in violation of Kasha's rule

Author:

Zhang Zijing1,Arias Jose Jonathan Rubio1,Kaehr Hana1,Liu Yujia2ORCID,Murata Ryoga2,Unno Masafumi2ORCID,Yodsin Nuttapon3,Pimbaotham Pimjai4,Jungsuttiwong Siriporn4ORCID,Rammo Matt5,Heo Jung-Moo1,Kim Jinsang1ORCID,Rebane Aleksander6,Laine Richard M.1ORCID

Affiliation:

1. Department of Mater. Sci. and Engin., Macromolecular Science and Eng. Center University of Michigan, Ann Arbor, 48109-21236, USA

2. Department of Chemistry and Chemical Biology, Graduate School of Science and Technology Gunma University, Kiryu 376-8515, Japan

3. Department of Chemistry, Faculty of Science, Silpakorn University, Nakorn Pathom 73000, Thailand

4. Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Ubon Ratchathani University, Ubon Ratchathani 34190, Thailand

5. National Institute of Chemical Physics and Biophysics, Tallinn, Estonia

6. Montana State University, Bozeman, MT 59717, USA

Abstract

Fluorescence emission λmax red-shifts with increasing DP in Vy4HC co-oligomers.

Funder

Eesti Teadusfondi

National Science Foundation

New Energy and Industrial Technology Development Organization

Publisher

Royal Society of Chemistry (RSC)

Reference45 articles.

1. M. G.Voronkov and V. I.Lavrent'yev , in Inorganic Ring Systems , Springer Berlin Heidelberg , Berlin, Heidelberg , 1982 , vol. 102 , pp. 199–236

2. Polyhedral Oligomeric Silsesquioxanes (Poss): Silicon Based Monomers and their Use in the Preparation of Hybrid Polyurethanes

3. Silsesquioxanes

4. G.Calzaferri , in Tailor-made Silicon-Oxygen Compounds , Friedr. Vieweg & SohnmbH , 1996 , pp. 149–169

5. J.Lichtenhan , in Polymeric Materials Encyc , CRC Press , NY , 1996 , vol. 10 , pp. 7768–7777

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