Mechanism of Initiation Stereocontrol in Polymerization of rac-Lactide by Aluminum Complexes Supported by Indolide

Mechanism of Initiation Stereocontrol in Polymerization of rac-Lactide by Aluminum Complexes Supported by Indolide–Imine Ligands

Published:2020-02-18 Issue:5 Volume:53 Page:1809-1818
ISSN:0024-9297
Container-title:Macromolecules
language:en
Short-container-title:Macromolecules

Author:

Luke Anna M.¹²^ORCID,Peterson Appie³⁴^ORCID,Chiniforoush Sina¹²⁵^ORCID,Mandal Mukunda¹²⁵^ORCID,Popowski Yanay³⁴^ORCID,Sajjad Hussnain¹^ORCID,Bouchey Caitlin J.³^ORCID,Shopov Dimitar Y.³^ORCID,Graziano Brendan J.¹^ORCID,Yao Letitia J.¹^ORCID,Cramer Christopher J.¹²⁵^ORCID,Reineke Theresa M.¹²^ORCID,Tolman William B.³⁴^ORCID

Affiliation:

1. Department of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, United States

2. NSF Center for Sustainable Polymers, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, United States

3. Department of Chemistry, Washington University in St. Louis, Campus Box 1134, 1 Brookings Drive, St. Louis, Missouri 63130, United States

4. NSF Center for Sustainable Polymers, Washington University in St. Louis, St. Louis, Missouri 63130, United States

5. Supercomputing Institute, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, United States

Funder

Division of Chemistry

Publisher

American Chemical Society (ACS)

Subject

Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.macromol.0c00092

Reference43 articles.

1. 50th Anniversary Perspective: There Is a Great Future in Sustainable Polymers

2. Recent developments in main group metal complexes catalyzed/initiated polymerization of lactides and related cyclic esters

3. Discrete Metal-Based Catalysts for the Copolymerization of CO2 and Epoxides: Discovery, Reactivity, Optimization, and Mechanism

4. Controlled Ring-Opening Polymerization of Lactide and Glycolide

5. Stereocontrolled ring-opening polymerisation of lactide

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