Photophysical Properties of Functionalized Double Decker Phenylsilsesquioxane Macromonomers: [PhSiO1.5]8[OSiMe2]2 and [PhSiO1.5]8[O0.5SiMe3]4. Cage-Centered Lowest Unoccupied Molecular Orbitals Form Even When Two Cage Edge Bridges Are Removed, Verified by Modeling and Ultrafast Magnetic Light Scattering Experiments
Author:
Affiliation:
1. Department of Chemistry and Center of Excellent for Innovation in Chemistry, Ubon Ratchathani University, Ubon 34190, Thailand
Funder
Division of Chemistry
Ministry of Higher Education, Research and Innovation
Center of Excellence for Innovation in Chemistry
Publisher
American Chemical Society (ACS)
Subject
Materials Chemistry,Inorganic Chemistry,Polymers and Plastics,Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.macromol.9b00700
Reference53 articles.
1. Molecules with Perfect Cubic Symmetry as Nanobuilding Blocks for 3-D Assemblies. Elaboration of Octavinylsilsesquioxane. Unusual Luminescence Shifts May Indicate Extended Conjugation Involving the Silsesquioxane Core
2. Synthesis and Photophysical Properties of Stilbeneoctasilsesquioxanes. Emission Behavior Coupled with Theoretical Modeling Studies Suggest a 3-D Excited State Involving the Silica Core
3. Fluoride Rearrangement Reactions of Polyphenyl- and Polyvinylsilsesquioxanes as a Facile Route to Mixed Functional Phenyl, Vinyl T10 and T12 Silsesquioxanes
4. Polyhedral Phenylsilsesquioxanes
5. Synthesis, characterization and photophysical properties of polyfunctional phenylsilsesquioxanes: [o-RPhSiO1.5]8, [2,5-R2PhSiO1.5]8, and [R3PhSiO1.5]8. compounds with the highest number of functional units/unit volume
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