Synthesis and C−H Activation Reactions of Cyclometalated Complexes of Ir(III): Cp*(PMe3)Ir(CH3)+ Does Not Undergo Intermolecular C−H Activation in Solution via a Cyclometalated Intermediate-Reference-Cited by-同舟云学术

Synthesis and C−H Activation Reactions of Cyclometalated Complexes of Ir(III): Cp*(PMe3)Ir(CH3)+ Does Not Undergo Intermolecular C−H Activation in Solution via a Cyclometalated Intermediate

Published:1997-11-01 Issue:47 Volume:119 Page:11538-11539
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Luecke Hans F.¹,Bergman Robert G.¹

Affiliation:

1. Chemical Sciences Division, Lawrence Berkeley Laboratory and the Department of Chemistry University of California, Berkeley, California 94720

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja972340z

Reference18 articles.

1. Unusually Mild and Selective Hydrocarbon C-H Bond Activation with Positively Charged Iridium(III) Complexes

2. Facile intermolecular activation of carbon-hydrogen bonds in methane and other hydrocarbons and silicon-hydrogen bonds in silanes with the iridium(III) complex Cp*(PMe3)Ir(CH3)(OTf)

3. Synthesis of Fischer Carbene Complexes of Iridium by C−H Bond Activation of Methyl and Cyclic Ethers: Evidence for Reversible α-Hydrogen Migration

4. Methane Metathesis at a Cationic Iridium Center

5. An Energetically Feasible Mechanism for the Activation of the C−H Bond by the 16-Electron CpM(PH3)(CH3)+ (M = Rh, Ir) Complex. A Theoretical Study

Cited by 75 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Mechanistic Understanding of Ru‐Catalyzed CH Functionalization Reactions;Handbook of CH‐Functionalization;2022-10

2. Relationship Between Energy Landscape Shape and Dynamics Trajectory Outcomes for Methane C–H Activation by Cationic Cp*(PMe3)Ir/Rh/Co(CH3);Organometallics;2020-04-08

3. Direct dynamics analysis of the cationic Cp*(PMe3)Ir(CH3) methane C–H activation mechanism;Faraday Discussions;2019

4. Catalytic Borylation of Methane: Combining Computational and High-Throughput Screening Approaches to Discover a New Catalyst;Alkane Functionalization;2018-12-28

5. Dynamical Mechanism May Avoid High-Oxidation State Ir(V)–H Intermediate and Coordination Complex in Alkane and Arene C–H Activation by Cationic Ir(III) Phosphine;Journal of the American Chemical Society;2018-08-01