An Energetically Feasible Mechanism for the Activation of the C−H Bond by the 16-Electron CpM(PH3)(CH3)+ (M = Rh, Ir) Complex. A Theoretical Study
Author:
Affiliation:
1. Contribution from the Department of Chemistry, National Tsing Hua University, Hsinchu 30043, Taiwan, ROC
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja961847r
Reference33 articles.
1. Homogeneous catalytic activation of carbon-hydrogen bonds
2. Unusually Mild and Selective Hydrocarbon C-H Bond Activation with Positively Charged Iridium(III) Complexes
3. Cationic Iridium(III) Complexes: A Step Towards Synthetic Applicability of CH Activation
4. Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups
5. Activation of Alkanes with Organotransition Metal Complexes
Cited by 98 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Cyclopentadienyl Complexes of IrIII for Attempted C−D Bond Activation;European Journal of Inorganic Chemistry;2023-07-28
2. A model study on the photodecarbonyl reaction of (η5-C5H5)M(CO)2 (M = Co, Rh, Ir);RSC Advances;2018
3. Methane Is the Best Substrate for C(sp3)–H Activation with Cp*(PMe3)Co(Me)(OTf): A Density Functional Theory Study;Organometallics;2015-08-06
4. 1,4- and 1,3-Metal Migration in a Cp*IrIII Complex: Experimental Evidence of Direct 1,3-Metal Migration;Organometallics;2014-07-22
5. Rhodium‐Catalyzed Spirocyclic Sultam Synthesis by [3+2] Annulation with Cyclic N ‐Sulfonyl Ketimines and Alkynes;Chemistry – A European Journal;2013-11-04
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3