Mechanistic and Kinetic Investigation on the Formation of Palladacyclopentadiene Complexes. A Novel Interpretation Involving a Bimolecular Self-Reaction of a Monoalkyne Intermediate
Author:
Affiliation:
1. Van’t Hoff Institute for Molecular Sciences, Nieuwe Achtergracht 166, 1018WV Amsterdam, The Netherlands, and Dipartimento di Chimica, Università Caʼ Foscari, Calle Larga S. Marta 2137, 30123 Venezia, Italy
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om8002398
Reference40 articles.
1. Cobaltacyclopentene complex as an intermediate in cobalt-catalyzed cooligomerization of diphenylacetylene with cyano olefins
2. Cobalt metallocycles. 6. Preparation and structure of cobaltacyclopentene complexes and their reactions with olefins and acetylenes
3. A Ru Catalyzed Addition of Alkenes to Alkynes
4. Catalytic Double Addition of Diazo Compounds to Alkynes: Synthesis of Functional Conjugated Dienes
5. Synthesis of multisubstituted 1,3-butadienes using the ruthenium-catalysed double addition of trimethylsilyldiazomethane to alkynylboronates
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