Reactivity of N-heterocyclic carbene–pyridine palladacyclopentadiene complexes toward halogen addition. The unpredictable course of the reaction-Reference-Cited by-同舟云学术

Reactivity of N-heterocyclic carbene–pyridine palladacyclopentadiene complexes toward halogen addition. The unpredictable course of the reaction

Published:2017 Issue:31 Volume:46 Page:10399-10407
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Visentin Fabiano¹²³⁴,Santo Claudio¹²³⁴,Scattolin Thomas¹²³⁴,Demitri Nicola⁵⁶⁴,Canovese Luciano¹²³⁴^ORCID

Affiliation:

1. Dipartimento di Scienze Molecolari e Nanosistemi

2. Università Ca’ Foscari

3. Venice

4. Italy

5. Elettra – Sincrotrone Trieste

6. Trieste

Abstract

Novel Pd(ii) complexes characterized by a ten term coordinative ring have been obtained when palladacyclopentadienyl complexes were reacted with I₂. The rearrangement kinetics, and a computational study suggesting a plausible mechanism are reported.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02162C

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5. Preparation structure, and role of tetrakis(methoxycarbonyl)palladiacyclopentadiene cyclic diolefin complexes in selective palladium-catalyzed cyclocotrimerization of acetylenes with olefins

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