Reactivity of N-heterocyclic carbene–pyridine palladacyclopentadiene complexes toward halogen addition. The unpredictable course of the reaction

Author:

Visentin Fabiano1234,Santo Claudio1234,Scattolin Thomas1234,Demitri Nicola564,Canovese Luciano1234ORCID

Affiliation:

1. Dipartimento di Scienze Molecolari e Nanosistemi

2. Università Ca’ Foscari

3. Venice

4. Italy

5. Elettra – Sincrotrone Trieste

6. Trieste

Abstract

Novel Pd(ii) complexes characterized by a ten term coordinative ring have been obtained when palladacyclopentadienyl complexes were reacted with I2. The rearrangement kinetics, and a computational study suggesting a plausible mechanism are reported.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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