Unusual Regioselectivity in the Aldehyde Addition Reactions of Allenyl/Propargyl Zirconium Complexes Derived from γ-(2-Pyridyl)propargyl Ethers: Synthesis of Multisubstituted α-Hydroxyallenes
Author:
Affiliation:
1. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, People’s Republic of China
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om301007z
Reference71 articles.
1. Chiral Allylic and Allenic Metal Reagents for Organic Synthesis
2. Palladium Pincer Complex-Catalyzed Trimethyltin Substitution of Functionalized Propargylic Substrates. An Efficient Route to Propargyl- and Allenyl-Stannanes
3. Synthesis of Enantiomerically Enriched Allenes by (−)-Sparteine-Mediated Lithiation of Alkynyl Carbamates
4. Propargyl and allyl Grignard and zinc reagents. Regioselective alkylation and its application to the synthesis of PGE3 and F3.alpha. methyl ester
5. Addition of Allenylzinc Reagents, Prepared in Situ from Nonracemic Propargylic Mesylates, to Aldehydes. A New Synthesis of Highly Enantioenriched Homopropargylic Alcohols
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