Addition of Allenylzinc Reagents, Prepared in Situ from Nonracemic Propargylic Mesylates, to Aldehydes. A New Synthesis of Highly Enantioenriched Homopropargylic Alcohols
Author:
Affiliation:
1. Department of Chemistry, University of Virginia, Charlottesville, Virginia 22901
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo9823083
Reference18 articles.
1. Synthesis of Chiral Enantioenriched Homopropargylic Alcohols from Propargylic Mesylates via Chiral Allenylzinc Intermediates
2. Unique regio- and stereoselectivity in the allylation of benzaldehyde with 2-substituted allylzincs generated by umpolung of π-allylpalladium
3. Propargylation of Carbonyl Compounds by Umpolung of Propargylpalladium Complexes with Diethylzinc
4. Highly Stereoselective Allylation of Benzaldehyde: Generation of a Stereochemically Defined Allylzinc Species from aπ-Allylpalladium Intermediate and Diethylzinc
5. Use of π-allylpalladium as a nucleophile via an alkyl-allyl exchange reaction with alkylzinc
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