Structure and Properties of Halogeno(hydrido)(triorganosilyl)rhodium(III) Complexes, RhX(H)(SiR1nR23-n)(PPh3)2 (X = Cl, I; R1 = OSiMe3, OEt, R2 = Me). Influence of the Alkoxy Groups and Halo Ligand on Stability and Reactivity of the Complexes-Reference-Cited by-同舟云学术

Structure and Properties of Halogeno(hydrido)(triorganosilyl)rhodium(III) Complexes, RhX(H)(SiR1nR23-n)(PPh3)2 (X = Cl, I; R1 = OSiMe3, OEt, R2 = Me). Influence of the Alkoxy Groups and Halo Ligand on Stability and Reactivity of the Complexes

Published:2002-02-01 Issue:5 Volume:21 Page:825-831
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Nishihara Yasushi¹,Takemura Miwa¹,Osakada Kohtaro¹

Affiliation:

1. Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om010862o

Reference53 articles.

1. Rhodium-silicon complexes

2. Organosilicon chemistry. Part V. Rhodium(III)–silyl complexes and the hydrosilation of hex-1-ene

3. Organosilicon chemistry. Part XII. Stability and catalytic activity of some chlorohydridobis(phosphine)(silyl)rhodium(III) complexes

4. Organosilicon chemistry. Part 24. Homogeneous rhodium-catalysed hydrosilation of alkenes and alkynes: the role of oxygen or hydroperoxides

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