Insertion of Isocyanides into Group 4 Metal−Carbon and Metal−Nitrogen Bonds. Syntheses and DFT Calculations
Author:
Affiliation:
1. Centro de Química Estrutural, Instituto Superior Técnico, Avenida Rovisco Pais no. 1, 1049-001 Lisboa, Portugal
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om030211n
Reference78 articles.
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2. Alkyl Alkyne Mono((trimethylsilyl)cyclopentadienyl) Niobium Complexes. Synthesis and Chemical Behavior in Insertion Processes. X-ray Crystal Structures of [NbCp‘(CH2SiMe3)2(Me3SiCCSiMe3)] and [NbCp‘(NAr){η4-CH(SiMe3)C(SiMe3)C(CH2SiMe3)CH(SiMe3)}], (Cp‘ = η5-C5H4SiMe3, Ar = 2,6-Me2C6H3). DFT Studies of the Model Complexes [Nb(η5-C5H5)R2(HCCH)] (R = Cl, Me)
3. Reactivity of Group 4 Metal Alkyl and Metallacyclic Compounds Supported by Aryloxide Ligands Toward Organic Isocyanides
4. Amido−Imido Niobium Complexes with Chloro−Silyl- and Amino−Silyl-Functionalized Cyclopentadienyl Ligands
5. Tantalacyclobutane Complexes Containing the Potentially C,N,N‘-Coordinating Ligand [C6H4(CH2N(Me)CH2CH2NMe2)-2]- (CNN) and Their Reactivity with Carbon Monoxide and tert-Butyl Isocyanide. X-ray Molecular Structures of [Ta{CH2CH(Me)CH2-1,3}(CNN)(O-t-Bu)2], [Ta{CH2CH(Ph)CH2-1,3}(CNN)(O-t-Bu)2], [Ta{C(O)((CH2)3-1,3)}(CNN)(O-t-Bu)2], and [Ta{C(N-t-Bu)CH2CH(Ph)CH2-1,4}(CNN)(O-t-Bu)2]
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