Nuclear Resonance Vibrational Spectroscopic Definition of the Fe(IV)2 Intermediate Q in Methane Monooxygenase and Its Reactivity

Author:

Jacobs Ariel Benjamin1,Banerjee Rahul2ORCID,Deweese Dory Ellen1,Braun Augustin1ORCID,Babicz Jeffrey Thomas1,Gee Leland Bruce1,Sutherlin Kyle David1,Böttger Lars Hendrik1,Yoda Yoshitaka3,Saito Makina4,Kitao Shinji5,Kobayashi Yasuhiro5,Seto Makoto5,Tamasaku Kenji6,Lipscomb John D.2ORCID,Park Kiyoung7ORCID,Solomon Edward I.18ORCID

Affiliation:

1. Department of Chemistry, Stanford University, 333 Campus Drive, Stanford, California 94305, United States

2. Department of Biochemistry, Molecular Biology and Biophysics, University of Minnesota, Minneapolis, Minnesota 55391, United States

3. Japan Synchrotron Radiation Research Institute, Hyogo 679-5198, Japan

4. Department of Physics, Graduate School of Science, Tohoku University, Sendai, Miyagi 980-8578, Japan

5. Institute for Integrated Radiation and Nuclear Science, Kyoto University, Osaka 590-0494, Japan

6. RIKEN SPring-8 Center, RIKEN, Sayo, Hyogo 679-5148, Japan

7. Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea

8. Stanford Synchrotron Radiation Light Source, SLAC National Accelerator Laboratory, Stanford University, Menlo Park, California 94025, United States

Funder

National Research Foundation of Korea

National Institutes of Health

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

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