Trapping an Elusive Fe(IV)-Superoxo Intermediate Inside a Self-Assembled Nanocage in Water at Room Temperature

Author:

Gera Rahul12ORCID,De Puja3,Singh Kundan K.45,Jannuzzi Sergio A. V.6ORCID,Mohanty Aisworika1,Velasco Lucia7,Kulbir 8ORCID,Kumar Pankaj8ORCID,Marco J. F.9,Nagarajan Kalaivanan1,Pecharromán Carlos7,Rodríguez-Pascual P. M.7,DeBeer Serena6ORCID,Moonshiram Dooshaye7ORCID,Gupta Sayam Sen3ORCID,Dasgupta Jyotishman1ORCID

Affiliation:

1. Department of Chemical Sciences, Tata Institute of Fundamental Research, Mumbai 400005, India

2. Department of Education in Science and Mathematics, Regional Institute of Education - Mysuru, NCERT, Mysuru 570006, India

3. Department of Chemical Sciences, Indian Institute of Science Education and Research Kolkata, Mohanpur, West Bengal 741246, India

4. Chemical Engineering Division, CSIR-National Chemical Laboratory, Pune, Maharashtra 411008, India

5. Chemistry Department, Indian Institute of Technology, Dharwad 580007, India

6. Department of Inorganic Spectroscopy, Max Planck Institute for Chemical Energy Conversion, Stiftstr. 34-36, Mülheim an der Ruhr 45470, Germany

7. Instituto de Ciencia de Materiales de Madrid Consejo Superior de Investigaciones Científicas Sor Juana Inés de la Cruz, 3, Madrid 28049, Spain

8. Department of Chemistry, Indian Institute of Science Education and Research (IISER), Tirupati 517507, India

9. Instituto de Quimica Fisica Blas Cabrera, Consejo Superior de Investigaciones Científicas, Serrano 119, Madrid 28006, Spain

Funder

Council of Scientific and Industrial Research, India

Consejo Superior de Investigaciones Cient?ficas

Ministerio de Ciencia, Innovaci?n y Universidades

Department of Atomic Energy, Government of India

Science and Engineering Research Board

Ministerio de Ciencia e Innovaci?n

Max-Planck-Gesellschaft

Publisher

American Chemical Society (ACS)

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