Structural Effects on the β-Scission Reaction of Tertiary Arylcarbinyloxyl Radicals. The Role of α-Cyclopropyl and α-Cyclobutyl Groups
Author:
Affiliation:
1. Dipartimento di Scienze e Tecnologie Chimiche, Università “Tor Vergata”, Via della Ricerca Scientifica, 1 I-00133 Rome, Italy
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo050883i
Reference47 articles.
1. The Effect of Ring Substitution on the O-Neophyl Rearrangement of 1,1-Diarylalkoxyl Radicals. A Product and Time-Resolved Kinetic Study
2. Spectral Properties and Absolute Rate Constants for β-Scission of Ring-Substituted Cumyloxyl Radicals. A Laser Flash Photolysis Study
3. Variable Trends in R−X Bond Dissociation Energies (R = Me, Et, i-Pr, t-Bu)
4. Pauling's Electronegativity Equation and a New Corollary Accurately Predict Bond Dissociation Enthalpies and Enhance Current Understanding of the Nature of the Chemical Bond
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