Coupling of Alkynes Mediated by [RuCp(PPh2NHPh)(CH3CN)2]+: Formation of η4-Butadiene Amido Complexes through Migration and N−H Activation of the PPh2NHPh Ligand-Reference-Cited by-同舟云学术

Coupling of Alkynes Mediated by [RuCp(PPh2NHPh)(CH3CN)2]+: Formation of η4-Butadiene Amido Complexes through Migration and N−H Activation of the PPh2NHPh Ligand

Published:2003-03-11 Issue:8 Volume:22 Page:1771-1774
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Pavlik Sonja¹,Mereiter Kurt¹,Schmid Roland¹,Kirchner Karl¹

Affiliation:

1. Institute of Applied Synthetic Chemistry and Institute of Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9, A-1060 Vienna, Austria

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om020990s

Reference12 articles.

1. [RuCp(PR3)(CH3CN)2]PF6 (R = Ph, Me, Cy). Convenient Precursors for Mixed Ruthenium(II) and Ruthenium(IV) Half-Sandwich Complexes

2. Selective CC Bond Formation between Alkynes Mediated by the [RuCp(PR3)]+ Fragment Leading to Allyl, Butadienyl, and Allenyl Carbene Complexes—An Experimental and Theoretical Study

3. Reactions of coordinated ligands. Part 47. Synthesis, structure, and reactivity of [.eta.4(5e)-butadienyl]ruthenium complexes: crystal structures of CpRu:C(Ph)-.eta.3-[C(Ph)C(Ph)CH(Ph)], CpRuC(Ph):C(Ph)-.eta.2-[C(Ph):CH(Ph)]P(OMe)3, and CpRu2[.mu.-(Z)-C(Ph):CH(Ph)](CO)2(.eta.4-C4Ph4)

4. Reactions of RuCp and RuCp* Allyl Carbene Complexes: Products Derived from Activation of Phenyl, Cyclohexyl, and Methyl C−H Bonds in PPh3, PCy3, and Cp* Ligands

5. Preparation of the Octahedral d6 Amido Complex TpRu(CO)(PPh3)(NHPh) (Tp = Hydridotris(pyrazolyl)borate): Solid-State Structural Characterization and Reactivity

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