Reversible Migratory Insertion/β-Alkyl Elimination in α-Agostic Alkylniobium Alkyne Complexes
Author:
Affiliation:
1. Contribution from the Laboratoire de Chimie de Coordination du CNRS, UPR 8241, 205 Route de Narbonne, 31077 Toulouse Cedex 4, France
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja963697q
Reference66 articles.
1. Acetylene and Allene Complexes: Their Implication in Homogeneous Catalysis
2. Mechanism, regiochemistry, and stereochemistry of the insertion reaction of alkynes with methyl(2,4-pentanedionato)(triphenylphosphine)nickel. A cis insertion that leads to trans kinetic products
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