Reaction of a Heterobimetallic Polyhydrido Cluster, [Cp*Ru(μ-H)4OsCp*] (Cp* = η5-C5Me5), with Diphenylacetylene. Regioselective C−H Bond Activation at the Osmium Center
Author:
Affiliation:
1. Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om700606q
Reference41 articles.
1. Heterobimetallic Polyhydride Complex, Cp*Ru(μ-H)4OsCp* (Cp* = η5-C5Me5). Synthesis and Reaction with Ethylene
2. Synthesis, Structure, and Chemistry of a Dinuclear Tetrahydride-Bridged Complex of Ruthenium, (.eta.5-C5Me5)Ru(.mu.-H)4Ru(.eta.5-C5Me5). C-H Bond Activation and Coupling Reaction of Ethylene on Dinuclear Complexes
3. An Unusual Example of Allyl-to-Alkynyl Migration in a Phenylacetylide-Bridged Heterobinuclear Complex of Rhodium and Iridium
4. Reactivity of the Heterobinuclear Phenylacetylide-Bridged A-Frame [RhIr(CO)2(μ-CCPh)(Ph2PCH2PPh2)2][O3SCF3] with Small Molecules
5. Heterobinuclear Vinyl, Allyl, and Related Complexes of Rhodium/Osmium from Terminal Alkynes and Allenes, Vinyl to Carbene Transformations, and the Structures of [RhOs(C(CH3)CH2)(CO)3(Ph2PCH2PPh2)2] and [RhOs(C(CH3)C(CH3)2)(CH3)(CO)3(Ph2PCH2PPh2)2][CF3SO3]
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