Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes-Reference-Cited by-同舟云学术

Insertion and C–C coupling processes in reactions of the unsaturated hydride [W2Cp2(H)(μ-PCy2)(CO)2] with alkynes

Published:2016 Issue:12 Volume:45 Page:5274-5289
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Alvarez M. Angeles¹²³⁴,García M. Esther¹²³⁴,García-Vivó Daniel¹²³⁴^ORCID,Ruiz Miguel A.¹²³⁴,Vega M. Fernanda¹²³⁴

Affiliation:

1. Departamento de Química Orgánica e Inorgánica/IUQOEM

2. Universidad de Oviedo

3. E-33071 Oviedo

4. Spain

Abstract

Alkyne insertion into the W–H bond invariably occurs in the title reactions, to give alkenyl complexes which may undergo further alkyne addition to yield hydrocarbyl-bridged derivatives generated from alkenyl–alkyne coupling.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04724B

Reference52 articles.

1. Synthesis and Reactivity of the Triply Bonded Binuclear Anion [W2(η5-C5H5)2(μ-PCy2)(μ-CO)2]−: Tungsten Makes a Difference

2. Hydride, gold(i) and related derivatives of the unsaturated ditungsten anion [W2Cp2(μ-PCy2)(μ-CO)2]−

3. The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds

4. Activation of Organic Substrates on Multi-Metallic Sites of Transition Metal Polyhydride Clusters Having C5Me5 Groups as Auxiliary Ligands

5. Dinuclear Ruthenium and Osmium Arene Trihydrido Complexes: Versatile Water-Soluble Synthons in Organometallic Chemistry

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Cyclic and Non-Cyclic Pi Complexes of Tungsten;Comprehensive Organometallic Chemistry IV;2022

2. A glimpse into the chemical reactivity of the unsaturated hydride [MoWCp2(H)(μ-PCy2)(CO)2];Journal of Organometallic Chemistry;2021-03

3. N–O Bond Activation and Cleavage Reactions of the Nitrosyl-Bridged Complexes [M2Cp2(μ-PCy2)(μ-NO)(NO)2] (M = Mo, W);Inorganic Chemistry;2018-11-21

4. Acceptor Behavior and E–H Bond Activation Processes of the Unsaturated Heterometallic Anion [MoReCp(μ-PCy2)(CO)5]−(Mo═Re);Organometallics;2018-05-02

5. E–H Bond Activation and Insertion Processes in the Reactions of the Unsaturated Hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2];Inorganic Chemistry;2018-02-07