Reactions of the Dirhenium(II) Complexes Re2X4(dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 10.1 Synthesis and Characterization of the Complex [Re2Br3(μ-dppm)2(CO)2(CNXyl)]O3SCF3 and Several Isomeric Forms of [Re2Br3(μ-dppm)2(CO)(CNXyl)2]Y (Y = PF6, O3SCF3)
Author:
Affiliation:
1. Department of Chemistry, Purdue University, 1393 Brown Building, West Lafayette, Indiana 47907-1393
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic960270b
Reference19 articles.
1. Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X= Cl, Br; dppm = Ph2PCH2PPh2) with isocyanides. Part IX. New isomeric forms of the mixed carbonyl-isocyanide dirhenium(II) Complexes Re2 Cl4(dppm)2(CO)(CNxyl) and [Re2Cl3(dppm)2(CO)(CNxyl)2]O3SCF3 The X-ray crystal structure of [(xyl NC)2ClRe(?-dppm)2ReCl2(CO)] O3SCF3
2. Reactions of Re2Cl4(dppm)2 with carbon monoxide that proceed with retention of the metal-metal bond: synthesis of Re2Cl4(dppm)2(CO)n (n = 1, 2) and the structural characterization of Cl2Re(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CO)
3. Mixed carbonyl-isocyanide and carbonyl-nitrile complexes derived from the reactions of the multiply bonded dirhenium(II) complexes Re2X4(dppm)2(CO) (X = chloro or bromo-; dppm = Ph2PCH2PPh2). The structural characterization of Cl2Re(.mu.-Cl)(.mu.-dppm)2ReCl(CO) and Cl2Re(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CNxylyl)
4. Monocarbonyl Complexes of the Type Re2X4(.mu.-dppm)2(CO) (X = Cl, Br; dppm = Ph2PCH2PPh2) Revisited. Reactions of the Bromo Complex Re2Br4(.mu.-dppm)2(CO) with tert-Butyl and Xylyl Isocyanides
5. Reactions of the dicarbonyl complex Re2Cl4(dppm)2(CO)2 with nitriles and isocyanides. Synthesis of [Re2Cl3(dppm)2(CO)2L]n+ (n = 0, 1; L = RCN, RNC) and the structural characterization of [Re2Cl3(dppm)2(CO)2(NCC2H5)]PF6
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1. Spectroscopic, structural and computational studies of thiophenolato bridged dirhenium(III,III) complexes;Journal of Coordination Chemistry;2022-11-11
2. Novel dirhenium(III,III) complexes with bridging diphenylphosphinomethane and dithiocarbamato ligands: A combined experimental and theoretical study;Polyhedron;2021-10
3. Mixed carbonyl–nitrile complexes of dirhenium(II). The structural characterization and reactivity of salts of the [Re2Cl3(μ-dppm)2(CO)(NCMe)n]+ cations (dppm=Ph2PCH2PPh2, n=1 or 2);Journal of Organometallic Chemistry;2000-06
4. Reactions of the Dirhenium(II) Complexes Re2X4(μ-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 21.1 A Comparison with the Complexes Re2Cl4(μ-dppE)2 and Re2Cl4(μ-dcpm)2 (dppE = Ph2PC(CH2)PPh2; dcpm = Cy2PCH2PCy2) and the Structural Characterization of Complexes of the Types Re2Cl4(μ-LL)2(CNR), Re2Cl4(μ-LL)2(CNR)2, and [Re2Cl3(μ-LL)2(CNR)3]+ (LL = dppm, dppE, dcpm; R = t-Bu, Xyl);Inorganic Chemistry;2000-05-19
5. Characterization of [Re2Cl3(mu-dppm)(2)(NCCH3)(2)][Cl] and [Re2Cl3(mu-dppm)(2)(NCC6H5)(2)][Cl]center dot 2CH(2)Cl(2) by X-ray crystallographic and two-dimensional NMR spectroscopic techniques;Journal of Cluster Science;2000
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