Alkyl Complexes of Group 4 Metals Containing a Tridentate-Linked Amido−Cyclopentadienyl Ligand: Synthesis, Structure, and Reactivity Including Ethylene Polymerization Catalysis
Author:
Affiliation:
1. Institut für Anorganische Chemie und Analytische Chemie, Johannes Gutenberg-Universität, J.-J.-Becher-Weg 24, D-55099 Mainz, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om980722n
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1. Scandium complex [{(.eta.5-C5Me4)Me2Si(.eta.1-NCMe3)}(PMe3)ScH]2: a unique example of a single-component .alpha.-olefin polymerization catalyst
2. Model Ziegler-Natta .alpha.-Olefin Polymerization Catalysts Derived from[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}(PMe3)Sc(.mu.2-H)]2 and[{(.eta.5-C5Me4)SiMe2(.eta.1-NCMe3)}Sc(.mu.2-CH2CH2CH3)]2. Synthesis, Structures, and Kinetic and Equilibrium Investigations of the Catalytically Active Species in Solution
3. Functionalized cyclopentadienyl ligands, IV. Synthesis and complexation of linked cyclopentadienyl‐amido ligands
4. Synthesis and Characterization of Zirconium Complexes Containing a Linked Amido-Fluorenyl Ligand
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