Mechanisms for Hydrogen-Atom Abstraction by Mononuclear Copper(III) Cores: Hydrogen-Atom Transfer or Concerted Proton-Coupled Electron Transfer?-Reference-Cited by-同舟云学术

Mechanisms for Hydrogen-Atom Abstraction by Mononuclear Copper(III) Cores: Hydrogen-Atom Transfer or Concerted Proton-Coupled Electron Transfer?

Published:2019-10-16 Issue:43 Volume:141 Page:17236-17244
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Mandal Mukunda¹^ORCID,Elwell Courtney E.¹^ORCID,Bouchey Caitlin J.¹²^ORCID,Zerk Timothy J.²,Tolman William B.²^ORCID,Cramer Christopher J.¹^ORCID

Affiliation:

1. Department of Chemistry, Minnesota Supercomputing Institute, Chemical Theory Center, and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, Minnesota 55455, United States

2. Department of Chemistry, Washington University in St. Louis, One Brookings Drive, Campus Box 1134, St. Louis, Missouri 63130, United States

Funder

Basic Energy Sciences

National Institute of General Medical Sciences

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.9b08109

Reference55 articles.

1. Copper Active Sites in Biology

2. Elaboration of copper–oxygen mediated C–H activation chemistry in consideration of future fuel and feedstock generation

3. Directed Hydroxylation of sp2 and sp3 C–H Bonds Using Stoichiometric Amounts of Cu and H2O2

4. Developing Mononuclear Copper–Active-Oxygen Complexes Relevant to Reactive Intermediates of Biological Oxidation Reactions

5. Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms

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